Rhodium-Catalyzed Highly Enantio- and Diastereoselective Cotrimerization of Alkenes and Dialkyl Acetylenedicarboxylates Leading to Furylcyclopropanes.

[摘要]：A cationic rhodium(I)/Segphos or H8-BINAP complex catalyzes the unprecedented cotrimerization of com. available monoenes and dialkyl acetylenedicarboxylates, leading to functionalized furylcyclopropanes, e.g. I (E = CO2R, R = Me, Et), with excellent enantioselectivity and perfect diastereoselectivity.

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