Palladium-Pincer Complex Catalyzed C-C Coupling of Allyl Nitriles with Tosyl Imines via Regioselective Allylic C-H Bond Functionalization.

[摘要]：A mechanistically new palladium-pincer complex catalyzed allylation of sulfonimines is presented. This reaction involves C-H bond functionalization of allyl nitriles under mild conditions. The reaction proceeds with a high regioselectivity, without allyl rearrangement of the product. Modeling studies indicate that the carbon-carbon bond formation process proceeds via (h1-allyl)palladium pincer complex intermediates.

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