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An Oxidation of Benzyl Methyl Ethers with NBS that Selectively Affords Either Aromatic Aldehydes or Aromatic Methyl Esters

  作者 MAYHOUB ABDELRAHMAN S; TALUKDAR ARINDAM; CUSHMAN MARK  
  选自 期刊  Journal of Organic Chemistry;  卷期  2010年75-10;  页码  3507-3510  
  关联知识点  
 

[摘要]Either mono- or dibromination of benzyl methyl ethers can be achieved by controlling the amount of NBS and the temperature. Elimination of methyl bromide from the monobrominated intermediates produces aromatic aldehydes, whereas hydrolysis of the dibrominated intermediates affords aromatic methyl esters in good yields.

 
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