Enantiomerically pure cyclopropylamines via C-B to C-N conversion.

[摘要]：Cyclopropyltrifluoroborates were utilized to form cyclopropylamines in a one-pot procedure. The scope was not only demonstrated by successfully reacting various racemic cis- and trans-2-substituted cyclopropanes as well as azides, but also by applying the sequence to enantiomerically pure building blocks. An approach to tranylcypromine and belactosin A is outlined.

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