New stereoselective synthesis of (Z)-a-iodovinylsilanes via one-pot iododesilylation/isomerization of 1,1-bis(silyl)alk-1-enes.

[摘要]：Synthetically useful (Z)-2-aryl-1-iodo-1-silylethenes were prepd. in good to excellent yields via one-pot monoiododesilylation/isomerization of readily accessible 2-aryl-1,1-bis(silyl)ethenes using N-iodosuccinimide or bis(pyridine)iodonium tetrafluoroborate under mild conditions.

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