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Boron trifluoride-diethyl etherate complex mediated allylation of Baylis-Hillman adducts: a facile synthesis of 1,5-dienes.

  作者 Yadav, Jhillu S.;Reddy, Basi V. Subba;Mandal, Satadru S.;Singh, Ashutosh Pratap;Basak, Ashok K.;  
  选自 期刊  Synthesis;  卷期  2008年-12;  页码  1943-1947  
  关联知识点  
 

[摘要]Morita-Baylis-Hillman adducts undergo smooth allylic nucleophilic substitution (SN2') with allyltrimethylsilane in the presence of BF3.OEt2 under mild reaction conditions to afford 1,5-diene derivs. in good yields with high selectivity.

 
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