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STEREOSELECTIVE SYNTHESIS OF THE FUSED gamma-LACTONE/delta-LACTONE CORE OF OPHIODILACTONES

  作者 MATSUBARA TAKAAKI; TAKAHASHI KEISUKE; ISHIHARA JUN; HATAKEYAMA SUSUMI  
  选自 期刊  Heterocycles;  卷期  2012年86-1;  页码  155-158  
  关联知识点  
 

[摘要]A promising precursor of ophiodilactones A and B, tetrameric phenyl propanoids isolated form the ophiuroid Ophiocoma scolopendrina, has been synthesized stereoselectively employing a halolactonization and an intramolecular epoxide-opening with a carboxylic acid as key reactions.

 
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