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Aryllithiums with Increasing Steric Crowding and Lipophilicity Prepared from Chlorides in Diethyl Ether. The First Directly Prepared Room-Temperature-Stable Dilithioarenes

  作者 SCRETTAS CONSTANTINOS G; STEELE BARRY R; MICHASCRETTAS MARIA; HEROPOULOS GEORGIOS A  
  选自 期刊  Organic Letters;  卷期  2012年14-22;  页码  5680-5683  
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[摘要]A convenient procedure has been developed for the preparation of synthetically useful, room-temperature-stable aryllithiums starting from aryl chlorides and lithium metal. The method provides a route to aryllithiums which have previously not been accessible cleanly or could only be prepared by using more expensive starting materials.

 
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