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Structure of 2,6-dinitrophenylsulfanylethanenitrile and 2,4,6-trinitrophenylsulfanylethanenitrile and their ring closure giving 2-cyanobenzo[d]thiazole-3-oxides.

  作者 Cerny, Jiri;Bertolasi, Valerio;Hanusek, Jiri;Machacek, Vladimir;  
  选自 期刊  Heterocycles;  卷期  2008年75-6;  页码  1425-1433  
  关联知识点  
 

[摘要]The base-catalyzed ring closure of 2,6-dinitrophenylsulfanylethanenitrile and 2,4,6-trinitrophenylsulfanylethanenitrile gives 2-cyano-7-nitrobenzo[d]thiazole-3-oxide and 2-cyano-5,7-dinitrobenzo[d]thiazole-3-oxide, resp. Structure of the starting phenylsulfanyl-ethanenitriles has been studied both in crystal and in soln.

 
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