ASYMMETRIC SYNTHESIS OF gamma-SILOXYENAMIDES VIA CHIRAL AUXILIARY-MEDIATED DIASETEROSELECTIVE COUPLING OF YNAMIDES, ALDEHYDES, AND SILANE BY NICKEL CATALYST

[摘要]：A nickel-catalyzed diastereoselective three-component coupling of optically active oxazolidinone-derived ynamides, aldehydes, and silane is described. The reaction proceeded via stereoselective formation of oxanickelacycle to give gamma-siloxyenamide derivatives in a highly diastereoselective manner.

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