【文章名】A New Synthesis of trans-2,3-Diaryloxiranes and 2-(1H-Benzo[d][1,2,3]triazol-1-yl)-1-arylethanols via the Reactions of 1-Benzyl-3-methylbenzotriazolium Ylide with Aryl Aldehydes
A New Synthesis of trans-2,3-Diaryloxiranes and 2-(1H-Benzo[d][1,2,3]triazol-1-yl)-1-arylethanols via the Reactions of 1-Benzyl-3-methylbenzotriazolium Ylide with Aryl Aldehydes
[摘要]:1-Benzyl-3-methylbenzotriazolium ylide was formed by the reaction of 1-benzyl-3-methylbenzotriazolium iodide with t-BuOK. Subsequently it reacted with various aryl aldehydes to give the corresponding trans-2,3-diaryloxiranes and 2-(1H-benzo[d][1,2,3]triazol-1-yl)-1-arylethanols in moderate to high yields.