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Pyridine/Potassium tert-Butoxide Catalyzed Benzannulation of beta-Diketones with Dimethyl Acetylenedicarboxylate

  作者 HU BIN; MENG LINGGUO; LIU YANLING; LIANG MAO; XUE SONG  
  选自 期刊  Synthesis;  卷期  2009年-24;  页码  4137-4142  
  关联知识点  
 

[摘要]A benzannulation reaction of beta-diketones with dimethyl acetylenedicarboxylate catalyzed by pyridine and potassium tert-butoxide is described. Fully substituted benzenes are synthesized from simple and commercially available starting materials under mild conditions in high yields.

 
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