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Fluorinated 5-and 7-membered carbacycle motifs by reaction of difluorocarbene with acetylene ethers

  作者 CHIA POH WAI; BELLO DAVIDE; SLAWIN ALEXANDRA M Z; OHAGAN DAVID  
  选自 期刊  Chemical Communications;  卷期  2013年49-22;  页码  2189-2191  
  关联知识点  
 

[摘要]The reaction of acetylene ethers with difluorocarbene (CF2), generated from the Ruppert-Prakash reagent, unexpectedly gave rise to co-produced fluorinated bicyclic [2.1.1]-hex-2-ene and cyclohepta-1,4-diene ring products.

 
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