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Biomimetic Oxidation of Alcohols Catalyzed by TEMPO-Functionalized Polyethylene Glycol and Copper(I) Chloride in Compressed Carbon Dioxide

  作者 MIAO CHENGXIA; HE LIANGNIAN; WANG JINQUAN; GAO JIAN  
  选自 期刊  SYNLETT;  卷期  2009年-20;  页码  3291-3294  
  关联知识点  
 

[摘要]Recyclable TEMPO-functionalized polyethylene glycol [PEG(6000)-(TEMPO)(2)] in combination with cuprous chloride were developed for biomimetic oxidation of a series of benzylic, allylic, heterocyclic alcohols, and 2-phenylethanol into the corresponding aldehydes or ketones in high selectivity and in moderate to high conversion in compressed CO2, which enhanced the catalytic activity as well as improved the selectivity.

 
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