Organocatalytic Synthesis of Terminal Propargylamine Derivatives by Tandem Amination-Alkynylation

[摘要]：The first organocatalytic synthesis of terminal propargylic amines from aldehydes via tandem amination/Seyferth-Gilbert alkynylation has been developed. The described protocol provides the formal addition products of acetylene (HC CH) to aliphatic imines, which are not easily obtained directly.

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