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Anisotropic volume change of poly(N-isopropylacrylamide)-based hydrogels with an aligned dual-network microstructure

  作者 WU JINGJUN; LIN YUTENG; SUN JIANZHONG  
  选自 期刊  Journal of Materials Chemistry;  卷期  2012年22-34;  页码  17449-17451  
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[摘要]A macroscopically anisotropic PEG-PNIPA hydrogel with a novel aligned dual-network microstructure has been fabricated, which displays a unique anisotropic two-dimensional shrinkage in response to a temperature increase. It consists of an aligned porous PEG scaffold as the primary network and PNIPA polymer inside the pores as the second network. The aligned porous PEG scaffold plays a critical role in achieving the anisotropic shrinkage by not only templating formation of the PNIPA microcylinders but also constraining the axial shrinkage of the cylindrical samples.

 
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