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Aryl Ketone Synthesis Via Tandem Orthoplatinated Triarylphosphite-Catalyzed Addition Reactions Of Arylboronic Acids with Aldehydes Followed by Oxidation

  作者 LIAO YUANXI; HU QIAOSHENG  
  选自 期刊  Journal of Organic Chemistry;  卷期  2010年75-20;  页码  6986-6989  
  关联知识点  
 

[摘要]Tandem orthoplatinated unaryl phosphate-catalyzed addition reaction of arylboromic acids with aldehydes followed by oxidation to yield anyl ketones is described. 3-Pentanone was identified as a suitable oxidant for the tandem aryl ketone formation reaction. By using micro-wave energy, aryl ketones were obtained in high yields with the catalyst lodading as low as 0.01%

 
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