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A Colorimetric Proton Sponge

  作者 SWOR CHARLES D; ZAKHAROV LEV N; TYLER DAVID R  
  选自 期刊  Journal of Organic Chemistry;  卷期  2010年75-20;  页码  6977-6979  
  关联知识点  
 

[摘要]1-8-Bis(dimethylammo)naphtlialene ("Proton Sponge") and bromomaleic anhyride lean quickly at room temperature). generating 3-(4.5-bis(dimethylammo)napthalen-1-yl)furan-2.5-dione (4-maleicanhydndopioton sponge or "MAPS") MAPS is a deep purple solid that exhibit positive solvato-chrormsin in solution. It is a weaker base than Proton Sponge When protona led in solution. MAPS loses us cohn but the color change can be reversed by deprotonation with a stronger base MAPS thus acts as a colorimetric version of a proton sponge

 
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