Nickel-Promoted Carboxylation/Cyclization Cascade of Allenyl Aldehyde under an Atmosphere of CO2

[摘要]：In the presence of a stoichiometric amount of Ni(0) complex, allenyl aldehydes smoothly reacted with carbon dioxide at an ambient temperature and pressure in a regioselective manner. The reaction involves an intramolecular cyclization of aldehyde and allene moieties to afford cyclic carboxylic acid derivatives having a hydroxyl group.

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