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Traceless Chelation-Controlled Rhodium-Catalyzed Intermolecular Alkene and Alkyne Hydroacylation

  作者 HOOPER JOEL F; YOUNG ROWAN D; WELLER ANDREW S; WILLIS MICHAEL C  
  选自 期刊  Chemistry-A European Journal;  卷期  2013年19-9;  页码  3125-3130  
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[摘要]A new functional-group tolerant, rhodium-catalyzed, sulfide-reduction process is combined with rhodium-catalyzed chelation-controlled hydroacylation reactions to give a traceless hydroacylation protocol. Aryl- and alkenyl aldehydes can be combined with both alkenes, alkynes and allenes to give traceless products in high yields. A preliminary mechanistic proposal is also presented.

 
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