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1,2,3-Triazole: Unique Ligand in Promoting Iron-Catalyzed Propargyl Alcohol Dehydration

  作者 YAN WUMING; YE XIAOHAN; AKHMEDOV NOVRUZ G; PETERSEN JEFFREY L; SHI XIAODONG  
  选自 期刊  Organic Letters;  卷期  2012年14-9;  页码  2358-2361  
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[摘要]A 1,2,3-traizole-promoted Iron(III)-catalyzed propargyl alcohol dehydration was developed for the synthesis of conjugated enynes. The desired conjugated enynes were prepared in good to excellent yields (up to 95%) with a large substrate scope and excellent stereoselectivity (only Z-isomers).

 
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