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[摘要]：A review. Arom. azides are widely used as starting materials in org. synthesis and as photoaffinity labeling reagents in mol. biol. When arom. azides have two or more nonequivalent azido groups, these groups can selectively react with dipolarophiles, nucleophiles, and reductants or undergo selective thermolysis and photolysis. Such selective reactions open up principally new ways for the directed synthesis of org. compds. and the use of arom. azides as photoaffinity labeling reagents. This account is devoted to all types of selective reactions on nonequivalent azido groups of arom. azides which were recently discovered and studied in the author's group. |
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