Ruthenium-Catalyzed Hydroarylations of Methylenecyclopropanes: Mild C-H Bond Functionalizations with Conservation of Cyclopropane Rings.

[摘要]：Ring conservation was obsd. in the 1st catalytic intermol. hydroarylation of methylenecyclopropanes (e.g. 2-phenylmethylenecyclopropane with 2-phenylpyridine catalyzed by RuCl2(cod) with dicyclohexyl(2',4',6'-triisopropylbiphenyl-2-yl)phosphine) via C-H bond functionalization, a remarkable reactivity mode for a transformation proceeding through (cyclopropylcarbinyl)metal intermediates.

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