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CuO Nanoparticles Catalyzed C-N, C-O, and C-S Cross-Coupling Reactions: Scope and Mechanism.

  作者 Jammi, Suribabu;Sakthivel, Sekarpandi;Rout, Laxmidhar;Mukherjee, Tathagata;Mandal, Santu;Mitra, Raja;Saha, Prasenjit;Punniyamurthy, Tharmalingam;  
  选自 期刊  Journal of Organic Chemistry;  卷期  2009年74-5;  页码  1971-1976  
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[摘要]CuO nanoparticles have been studied for C-N, C-O, and C-S bond formations via cross-coupling reactions of nitrogen, oxygen, and sulfur nucleophiles with aryl halides. Amides, amines, imidazoles, phenols, alcs. and thiols undergo reactions with aryl iodides in the presence of a base such as KOH, Cs2CO3, and K2CO3 at moderate temp. The procedure is simple, general, ligand-free, and efficient to afford the cross-coupled products in high yield.

 
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