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An efficient synthesis of optically active trifluoromethyl aldimines via asymmetric biomimetic transamination

  作者 LIU MAO; LI JING; XIAO XIAO; XIE YING; SHI YIAN  
  选自 期刊  Chemical Communications;  卷期  2013年49-14;  页码  1404-1406  
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[摘要]This communication describes a chiral base-catalyzed asymmetric [1,3]-proton shift of trifluoromethyl ketimines, giving a wide variety of trifluoromethyl aldimines containing various functional groups with up to 94% ee.

 
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