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Guest-mediated switching of the assembly state of a water-soluble deep-cavity cavitand

  作者 GAN HAIYING; GIBB BRUCE C  
  选自 期刊  Chemical Communications;  卷期  2013年49-14;  页码  1395-1397  
  关联知识点  
 

[摘要]Deep-cavity cavitand TEMOA (2) is shown to assemble via the hydrophobic effect into tetrameric and hexameric assemblies. With inner volumes of 1400-1500 angstrom(3) and 3200-3700 angstrom(3) respectively, these well-defined and mono-dispersed assemblies represent the largest of their type to date.

 
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