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Structure Revision of Circumdatins A and B, Benzodiazepine Alkaloids Produced by Marine Fungus Aspergillus ostianus, by X-ray Crystallography.

  作者 Ookura, Ryuhei;Kito, Keijiro;Ooi, Takashi;Namikoshi, Michio;Kusumi, Takenori;  
  选自 期刊  Journal of Organic Chemistry;  卷期  2008年73-11;  页码  4245-4247  
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[摘要]The structures of circumdatins A and B, pentacyclic alkaloids produced by Aspergillus ostianus, were revised from the previously reported betaine structures I (R = MeO, H, resp.) to unique oxepin ones II by X-ray crystallog. The co-occurring known alkaloids, circumdatins D, E, and H, and a new compd. reported here, circumdatin J III, have a common framework.

 
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