Simple Synthesis of beta-Trifluoromethylstyrenes Using (E)-Trimethyl-(3,3,3-trifluoroprop-1-enyl)silane

[摘要]：(E)-Trimethyl-(3,3,3-trifluoroprop-1-enyl)silane (1) was synthesized as a reagent for use In Hiyama cross-coupling reactions for the production of beta-trifluoromethylstyrene derivatives. Cross-coupling of 1 with electronically diverse aryl iodides was achieved by treatment with CsF In the presence of catalytic amounts of palladium to afford the desired products In moderate to good yields.

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