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SYNTHESIS OF p-CHLOROAZACALIX[5]ARENE PENTAMETHYL ETHER: RING SIZE-DEPENDENT DEPROTECTION OF N-BENZYL GROUPS

  作者 TSUE HIROHITO; MIYATA KAZUYUKI; TAKAHASHI DAISUKE; TAKAHASHI HIROKI; SASAKI KOHEI; TAMURA RUI  
  选自 期刊  Heterocycles;  卷期  2012年86-1;  页码  159-164  
  关联知识点  
 

[摘要]Syntheses of chlorinated azacalix[4]arene and azacalix[5]arene have been investigated. While the preparation of the former failed in the final N-debenzylation step, the latter was successfully obtained. The observed ring size-dependent deprotection was interpreted by steric effect.

 
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