Enantioselective Radical Conjugate Addition to a'-Phosphoric Enones.

[摘要]：Catalytic enantioselective radical conjugate addn. reactions using a'-phosphoric enone templates have been studied. The C2-sym. bisoxazoline-zinc(II) complex proves to be effective for high enantioselectivities and chem. yields. In addn., intermediate a-carbonyl alkyl radicals could be trapped with allyltributylstannane to afford anti-isomers as major products with high enantioselectivities.

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