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Synthesis of Few-Layer Hexagonal Boron Nitride Thin Film by Chemical Vapor Deposition

  作者 Shi, YM; Hamsen, C; Jia, XT; Kim, KK; Reina, A; Hofmann, M; Hsu, AL; Zhang, K; Li, HN; Juang, ZY; Dresselhaus, MS; Li, LJ; Kong, J  
  选自 期刊  Nano Letters;  卷期  2010年10-10;  页码  4134-4139  
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[摘要]In this contribution we demonstrate a method of synthesizing a hexagonal boron nitride (h-BN) thin him by ambient pressure chemical vapor deposition on polycrystalline Ni films Depending on the growth conditions, the thickness of the obtained h-BN film is between similar to 5 and 50 nm. The h-ON grows continuously on the entire Ni surface and the region with uniform thickness can be up to 20 mu m in lateral size which is only limited by the size of the Ni single crystal grains The hexagonal structure was confirmed by both electron and X-ray diffraction X-ray photoelectron spectroscopy shows the B/N atomic ratio to be 1112 angstrom large optical band gap (5 92 eV) was obtained from the photoabsorpoon spectra which suggest the potential usage of this h-ON film in optoelectronic devices

 
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