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Palladium-Mediated Olefination of 2-(tert-Butyldimethylsilyl)pyridine by sp(3) C-H Activation

  作者 WANG CONG; GE HAIBO  
  选自 期刊  Synthesis;  卷期  2011年-16;  页码  2590-2594  
  关联知识点  
 

[摘要]An unprecedented direct alkenylation of 2-(tert-butyldimethylsilyl)pyridine with acrylates through palladium-mediated C-H activation on a nonacidic sp(3) carbon is reported. This method provides an efficient approach to allylsilanes.

 
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