Palladium-Mediated Olefination of 2-(tert-Butyldimethylsilyl)pyridine by sp(3) C-H Activation
[摘要]:An unprecedented direct alkenylation of 2-(tert-butyldimethylsilyl)pyridine with acrylates through palladium-mediated C-H activation on a nonacidic sp(3) carbon is reported. This method provides an efficient approach to allylsilanes.
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