Palladium-Catalyzed Ligand-Directed Oxidative Functionalization of Cyclopropanes

[摘要]：This report describes the palladium-catalyzed functionalization of cyclopropanes containing oxazoline, oxime ether, and pyridine directing groups. Three different oxidants were examined in these studies: IOAc, PhI(OAc)(2), and benzoquinone. The reactions yielded products derived from 2 degrees sp(3) C-H functionalization and/or C-C activation of the cyclopropane ring. The outcome and the product distributions were highly dependent on the structure of the substrate and the nature of the oxidant.

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