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[摘要]:Two modified beta-cyclodextrins, H-2 and H-3, having a flexible appended moiety were studied for the chiral discrimination of the enantiomers of various amino acids by means of fluorescence as signaling option. These hosts quenched the fluorescence intensities of amino acids upon binding. The D-enantiomers were better recognized by these hosts. The association constants (K-s) and enantioselectivity factors (a) of the host guest complexes were calculated. |
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