Regio- and Diastereoselective Nickel-Catalyzed Allylation of Aromatic Aldehydes with alpha-Halo-beta,beta-difluoropropene Derivatives

[摘要]：A one-pot nickel-catalyzed allylation of aromatic aldehydes with alpha-halo-beta,beta-difluoropropene-containing compounds promoted by ZnEt2 under mild conditions was described. The reaction displays moderate to good regio- and diastereoselectivity, tolerates a wide range of functional groups, and provides an efficient method for the synthesis of gamma-fluorinated homoallylic alcohols.

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