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Stabilized alpha-Helix-Catalyzed Enantioselective Epoxidation of alpha,beta-Unsaturated Ketones

  作者 NAGANO MASANOBU; DOI MITSUNOBU; KURIHARA MASAAKI; SUEMUNE HIROSHI; TANAKA MASAKAZU  
  选自 期刊  Organic Letters;  卷期  2010年12-15;  页码  3564-3566  
  关联知识点  
 

[摘要]Chiral cyclic alpha-amino acid containing oligopeptide catalyzed highly enantioselective epoxidation of alpha,beta-unsaturated ketones and the alpha-helical secondary structure of the peptide catalyst were revealed by X-ray crystallographic analysis.

 
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