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Platinum-catalyzed tandem cyclization-Nazarov cylization reactions: an easy access to complex carbocyclic molecules from 2-alkenyl-(1'-hydroxyl-4-en-2-ynyl)benzenes.

  作者 Abu Sohel, Shariar Md.;Lin, Sheng-Hsun;Liu, Rai-Shung;  
  选自 期刊  SYNLETT;  卷期  2008年-5;  页码  745-750  
  关联知识点  
 

[摘要]In the presence of PtCl2/CO catalyst, 2-alkenyl-(1'-hydroxyl-4-en-2-ynyl)benzenes undergo a tandem electrophilic 6-exo-dig cyclization-Nazarov cyclization sequence to give 1H-cyclopenta[a]naphthalenes efficiently and regioselectively.

 
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