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SYNTHESES OF NOVEL DIBENZO[d,f]HETERONINS INCORPORATING GROUP 15 AND 16 HEAVIER ELEMENTS

  作者 YASUIKE SHUJI; TSUKADA SATOSHI; KAKUSAWA NAOKI; TSUCHIYA TAKASHI; KURITA JYOJI  
  选自 期刊  Heterocycles;  卷期  2012年86-2;  页码  941-945  
  关联知识点  
 

[摘要]Fully unsaturated dibenzo[d,f]heteronins incorporating Group 15 (P, As, Sb) and Group 16 (S, Se, Te) heavier elements have been prepared via a common 1,8-dilithium intermediate. These heteronins, except for dibenzothionin, are the first examples of fused nine-membered heterocyclic ring. Proton NMR spectra of the heteronins revealed that two olefinic bonds in the heteronin ring have the cis configurations and the nine-membered rings exist in a buckled, non-planar conformation.

 
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