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Nano Copper Oxide Catalyzed Synthesis of Symmetrical Diaryl Selenides via Cascade Reaction of KSeCN with Aryl Halides

  作者 REDDY K HARSHA VARDHAN; REDDY V PRAKASH; MADHAV B; SHANKAR J; NAGESWAR Y V D  
  选自 期刊  SYNLETT;  卷期  2011年-9;  页码  1268-1272  
  关联知识点  
 

[摘要]An unprecedented transfer of selenium ion from potassium selenocyanate was observed in C-Se cross-coupling reaction catalyzed by copper oxide nanoparticles under ligand-free conditions. Utilizing this protocol wide range of symmetrical diaryl selenides were obtained in excellent yields. Nano-CuO is recyclable up to four cycles without loss of catalytic activity.

 
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