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Palladium-Catalyzed Double Cross-Coupling Reaction of vic-Diborylalkenes and -arenes with vic-Bromo(bromomethyl)arenes

  作者 SHIMIZU MASAKI; TOMIOKA YOSUKE; NAGAO IKUHIRO; HIYAMA TAMEJIRO  
  选自 期刊  SYNLETT;  卷期  2009年-19;  页码  3147-3150  
  关联知识点  
 

[摘要]Efficient annulation of vic-diborylalkenes and -arenes with vic-bromo(bromomethyl)arenes has been achieved, Using Pd(PPh3)(4) as a catalyst in the presence of Cs2CO3 and water ill THF at 60 degrees C, giving rise to the corresponding indene and fluorene derivatives in good to high yields.

 
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