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Gold-Facilitated '6-Exo-dig' Intramolecular Cyclization of 2-[(2-Nitrophenyl)ethynyl]phenylacetic Acids: General Access to 5H-Benzo[b]carbazole-6,11-diones

  作者 SALAS CRISTIAN O; REBOREDO FRANCISCO J; ESTEVEZ JUAN C; TAPIA RICARDO A; ESTEVEZ RAMON J  
  选自 期刊  SYNLETT;  卷期  2009年-19;  页码  3107-3110  
  关联知识点  
 

[摘要]The preliminary results of a regiospecific synthesis of (Z)-1-(2-nitrobenzylidene)isochroman-3-ones by gold(I)-catalyzed cycloisomerization of phenylethynylacetic acids Under mild conditions is described. These novel lactones proved to be suitable starting materials for a new, general access to 5H-benzo[b]carbazole-6,11-diones.

 
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