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Mechanochemical synthesis of an yttrium based metal-organic framework

  作者 SINGH NIRAJ K; HARDI MEENAKSHI; BALEMA VIKTOR P  
  选自 期刊  Chemical Communications;  卷期  2013年49-10;  页码  972-974  
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[摘要]For the first time a metal hydride has been used for the preparation of a metal-organic framework. MIL-78 has been synthesized by the solid-state mechanochemical reaction between yttrium hydride and trimesic acid. The process does not involve solvents and does not generate liquid by-products, thus proving the viability of the solid-state approach to the synthesis of MOFs.

 
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