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Metallic zinc-assisted synthesis of Ti3+ self-doped TiO2 with tunable phase composition and visible-light photocatalytic activity

  作者 ZHENG ZHAOKE; HUANG BAIBIAO; MENG XIAODONG; WANG JUNPENG; WANG SHAOYING; LOU ZAIZHU; WANG ZEYAN; QIN XIAOYAN; ZHANG XIAOYANG; DAI YING  
  选自 期刊  Chemical Communications;  卷期  2013年49-9;  页码  868-870  
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[摘要]Stable Ti3+ self-doped TiO2 with tunable phase composition and highly efficient visible-light photoactivity (ca. 32.7 times stronger than an undoped sample for (OH)-O-center dot formation) was synthesized via a facile metallic zinc-assisted method. The surface Ti3+ species can be stabilized by Zn doping, and the photocatalytic selectivity can be regulated by the phase composition.

 
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