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[摘要]:A facile and high yielding synthesis of porphyrin appended thiazoles from the reaction of 5-(4-thiocarboxamidophenyl)-10,15,20-triphenylporphyrin with a-bromo ketones has been described. The fluorescence studies of synthesized porphyrin appended thiazoles in chloroform indicate that porphyrin p system is not greatly perturbed by substitution of a thiazole moiety at meso-phenyl ring even in the excited state. |
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