Claisen Rearrangement through Enolization of 2-Allyloxyindolin-3-ones: Construction of Adjacent Carbon Stereocenters in 3-Hydroxyindolin-2-ones

[摘要]：The Claisen rearrangement of 3-oxy-2-allyloxyindoles through base-induced enolization of 2-allyloxyindolin-3-ones was investigated. This rearrangement reaction proceeded smoothly at low temperature and showed intriguing diastereoselectivity that did not depend on the initial olefin geometry.

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