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Photoactivated Racemization Catalyst for Dynamic Kinetic Resolution of Secondary Alcohols

  作者 DO YOUNGSHIL; HWANG INCHUL; KIM MAHNJOO; PARK JAIWOOK  
  选自 期刊  Journal of Organic Chemistry;  卷期  2010年75-16;  页码  5740-5742  
  关联知识点  
 

[摘要]Household fluorescent light activates a diruthenium complex to generate catalytic species highly active for the racemization of secondary alcohols under ambient conditions. This catalyst system is applicable for the chemoenzymatic dynamic kinetic resolution of racemic alcohols to give optically pure acetates under mild conditions.

 
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