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Guanidine-annelated heterocycles XVI. A practical synthesis of 7-chloro-4-phenylamino[1,2,4]triazoloquinazolin-5(4H)-ones.

  作者 Hsu, Wen-Chuan;Shan, Pei-Wen;Huang, Yi-Chen;Liu, Kang-Chien;Chang, Tsu-Chung;  
  选自 期刊  Heterocycles;  卷期  2008年75-10;  页码  2421-2428  
  关联知识点  
 

[摘要]Triazolo[2,3-a]quinazolin-5(4H)-ones can be prepd. via Dimroth rearrangement by treatment of 6-chloro-2-hydrazino-3-phenylaminoquinazolin-4-one with RC(OEt)3 [R = H, Me, Et] by heating at 40 癈 more elevated temp. than the prepn. of their triazolo[4,3-a] isomers.

 
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