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Carbon with hierarchical pores from carbonized metal-organic frameworks for lithium sulphur batteries

  作者 XI KAI; CAO SHUAI; PENG XIAOYU; DUCATI CATERINA; KUMAR R VASANT; CHEETHAM ANTHONY K  
  选自 期刊  Chemical Communications;  卷期  2013年49-22;  页码  2192-2194  
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[摘要]This paper presents a novel method and rationale for utilizing carbonized MOFs for sulphur loading to fabricate cathode structures for lithium-sulphur batteries. Unique carbon materials with differing hierarchical pore structures were synthesized from four types of zinc-containing metal-organic frameworks (MOFs). It is found that cathode materials made from MOFs-derived carbons with highermesopore (2-50 nm) volumes exhibit increased initial discharge capacities, whereas carbons with higher micropore (<2 nm) volumes lead to cathode materials with better cycle stability.

 
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