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Urea-functionalized crystalline capsules for recognition and separation of tetrahedral oxoanions

  作者 CUSTELCEAN RADU  
  选自 期刊  Chemical Communications;  卷期  2013年49-22;  页码  2173-2182  
  关联知识点  
 

[摘要]The persistent ability of tripodal TREN-based tris-urea receptors (TREN = tris(2-aminoethyl) amine) to self-assemble with a variety of oxoanions into dimeric capsules upon crystallization is reviewed. The capsule crystallization allows for charge-, shape-, and size-selective encapsulation of tetrahedral XO4n anions (n = 2,3), and provides an effective way to separate these anions from competitive aqueous environments.

 
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