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Nucleophilic Substitution of Secondary Alkyl-Substituted Propargyl Acetates: An Economic and Practical Indium Trichloride Catalyzed Access

  作者 LIN MIN; HAO LU; LIU XIAOTAO; CHEN QINGZHEN; WU FENG; YAN PING; XU SUXIA; CHEN XINLIANG; WEN JIAJIE; ZHAN ZHUANGPING  
  选自 期刊  SYNLETT;  卷期  2011年-5;  页码  665-670  
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[摘要]An economic and practical transformation from secondary alkyl-substituted propargyl acetates to a variety of nucleophilic substitution products was described. This reaction was catalyzed by inexpensive InCl3. High yields and excellent chemoselectivity were obtained. The five-, six-, and seven-membered propargyl cycloethers were also successfully constructed by this protocol.

 
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